The power Hollywood couple will be hitting the stage at the Dolby Theatre in Los Angeles for the 2014 Academy Awards on Sunday evening to present one of the highly coveted statuettes.
They will be joined by last year's big winners, including Daniel Day-Lewis, Anne Hathaway, Christoph Waltz and Jennifer Lawrence, who will also present trophies to Sunday's Oscar winners.
The 86th Academy Awards will be hosted by TV icon Ellen DeGeneres
The American presenter said: "It's a great year to host, there are great movies nominated and fun people in the audience for me to play with.
"I'm not going to hurt anybody, but it will be fun. I kinda know everybody too: Julia [Roberts] is my friend, Meryl [Streep] is hilarious, Leo [DiCaprio] is fantastic. I did [movie] 'EDtv' with Matthew McConaughey, and I'll definitely have jokes with him."
The full list of presenters at the Oscars 2014:
• Amy Adams
• Kristen Bell
• Jessica Biel
• Jim Carrey
• Glenn Close
• Bradley Cooper
• Penélope Cruz
• Benedict Cumberbatch
• Viola Davis
• Daniel Day-Lewis
• Robert De Niro
• Zac Efron
• Sally Field
• Harrison Ford
• Jamie Foxx
• Andrew Garfield
• Jennifer Garner
• Whoopi Goldberg
• Joseph Gordon-Levitt
• Anne Hathaway
• Goldie Hawn
• Chris Hemsworth
• Kate Hudson
• Samuel L. Jackson
• Angelina Jolie
• Michael B. Jordan
• Anna Kendrick
• Jennifer Lawrence
• Matthew McConaughey
• Ewan McGregor
• Bill Murray
• Kim Novak
• Tyler Perry
• Brad Pitt
• Sidney Poitier
• Gabourey Sidibe
• Will Smith
• Kevin Spacey
• Jason Sudeikis
• Channing Tatum
• Charlize Theron
• John Travolta
• Christoph Waltz
• Kerry Washington
• Emma Watson
• Naomi Watts
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